In the fresh municipal solid waste incineration (MSWI) of bottom ash, samples the fractional composition of Zn, Cr and Co was investigated. The BCR method was utilised to evaluate the acid soluble and exchangeable fraction (F1), reducible fraction (F2), oxidizable fraction (F3) and residual fraction (F4). Physico-chemical parameters such as pH, dry mass, and pseudo-total metal content were also determined. The percentage of zinc in fractions was in the following order: F3 (31.8%) > F1 (30.6%) > F2 (27.8%) > F4 (9.8%), for chromium F4 (88.7%) > F3 (5.4%) > F1 (3.2%) > F2 (2.7%), and in the case of cobalt F4 (59.8%) > F1 (14.3%) > F2 (13.6%) > F3 (12.3%). Mobile metal pool (F1-F3) gathered the most of zinc (90.2 %) and the least of chromium (11.3%).