The Effect of Mineral Salt on Reactive Dye Removal from Aqueous Solutions by Ultrafiltration
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Ukryj
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Faculty of Environmental Engineering, Wrocław University of Science and Technology
Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
Autor do korespondencji
Katarzyna Majewska-Nowak
Faculty of Environmental Engineering, Wrocław University of Science and Technology,
Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
J. Ecol. Eng. 2022; 23(10):239–247
SŁOWA KLUCZOWE
DZIEDZINY
STRESZCZENIE
The effect of mineral salt on the reactive dye removal was evaluated by using flat
ultrafiltration (UF) membranes made of polyethersulfone (PES) and regenerated cellulose (C).
Five reactive dyes varied in molecular weight (Reactive Orange 16, Remazol Brilliant Blue R,
Reactive Orange 20, Reactive Black 5, Reactive Read 120) were used in the UF experiments.
The applied membranes were characterized by the cut-off value equal to 10 kDa. The
ultrafiltration process was performed in a dead-end mode under the transmembrane pressure of
0.2 MPa. Dye concentration in model solutions was equal to 100 mg/dm 3 . Two various mineral
salts (NaCl and Na 2 SO 4 ) were chosen to simulate the composition of dye-house baths. The
concentration of monovalent and divalent salt in model dye solutions amounted to 1–2 g/dm 3 .
Transport and separation properties of the UF membranes towards reactive dyes and mineral
salts were evaluated. It was found that the separation efficiency of all tested dyes was dependent
on the mineral salt presence. The effect of mineral salt on dye retention was more pronounced
for membrane made of regenerated cellulose (C) than for polyethersulfone membrane (PES). In
the case of the C membrane the dye retention coefficients varied in the wide range – from 55 to
83%, whereas for PES membrane the degree of dye separation was less diverse and amounted to
81–96%. The presence of mineral salt in water and dye solutions generally worsen the membrane
permeability due to osmotic pressure increase as well as enhancing adsorptive fouling of dye
particles in membrane matrix.