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Sustainable copper recovery from industrial effluents through iron screen-assisted cementation under stirred conditions
 
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Ukryj
1
a. Department of General Subjects, University of Business and Technology, Abdul-Rahman Faqih, 21361, Jeddah, Saudi Arabia. b. Chemical Engineering Department, Faculty of Engineering, Alexandria University, Elshatby, 21544, Alexandria, Egypt.
 
 
Autor do korespondencji
Mohamed Abbas Elnaggar   

a. Department of General Subjects, University of Business and Technology, Abdul-Rahman Faqih, 21361, Jeddah, Saudi Arabia. b. Chemical Engineering Department, Faculty of Engineering, Alexandria University, Elshatby, 21544, Alexandria, Egypt.
 
 
 
SŁOWA KLUCZOWE
DZIEDZINY
STRESZCZENIE
This study introduces a cementation system employing iron screens positioned within a mechanically stirred batch reactor for efficient copper extraction from wastewater. Systematic experimental investigations examined the influence of four operational parameters: initial copper concentration (0.01–0.03 M), agitation speed (100–800 rpm), reaction duration (up to 50 minutes), and number of iron screens (3–7). Results demonstrated that copper removal efficiency reached 82–88% under optimized conditions, with the process governed primarily by external mass transfer rather than surface reaction kinetics. Response Surface Methodology yielded a highly predictive quadratic model with good agreement between experimental and predicted values of copper removal (R² = 0.9846). Multi-objective optimization identified optimal operating parameters: 0.0295 M initial concentration, 757 rpm agitation intensity, 47.4 minutes reaction time, and three iron screens, achieving 87.57% copper recovery. The proposed system offers distinct advantages including operational simplicity, direct recovery of metallic copper, minimal chemical consumption, and straightforward industrial scalability. This work presents a sustainable, cost-effective solution for copper-bearing wastewater treatment that simultaneously addresses environmental protection and resource recovery imperatives.
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