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Sustainable copper recovery from industrial effluents through iron screen-assisted cementation under stirred conditions
 
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Ukryj
1
a. Department of General Subjects, University of Business and Technology, Abdul-Rahman Faqih, 21361, Jeddah, Saudi Arabia. b. Chemical Engineering Department, Faculty of Engineering, Alexandria University, Elshatby, 21544, Alexandria, Egypt.
 
 
Data publikacji: 19-01-2026
 
 
Autor do korespondencji
Mohamed Abbas Elnaggar   

a. Department of General Subjects, University of Business and Technology, Abdul-Rahman Faqih, 21361, Jeddah, Saudi Arabia. b. Chemical Engineering Department, Faculty of Engineering, Alexandria University, Elshatby, 21544, Alexandria, Egypt.
 
 
J. Ecol. Eng. 2026; 27(5)
 
SŁOWA KLUCZOWE
DZIEDZINY
STRESZCZENIE
This study introduces a cementation system employing iron screens positioned within a mechanically stirred batch reactor for efficient copper extraction from wastewater. Systematic experimental investigations examined the influence of four operational parameters: initial copper concentration (0.01–0.03 M), agitation speed (100–800 rpm), reaction duration (up to 50 minutes), and number of iron screens (3–7). Results demonstrated that copper removal efficiency reached 82–88% under optimized conditions, with the process governed primarily by external mass transfer rather than surface reaction kinetics. Response Surface Methodology yielded a highly predictive quadratic model with good agreement between experimental and predicted values of copper removal (R² = 0.9846). Multi-objective optimization identified optimal operating parameters: 0.0295 M initial concentration, 757 rpm agitation intensity, 47.4 minutes reaction time, and three iron screens, achieving 87.57% copper recovery. The proposed system offers distinct advantages including operational simplicity, direct recovery of metallic copper, minimal chemical consumption, and straightforward industrial scalability. This work presents a sustainable, cost-effective solution for copper-bearing wastewater treatment that simultaneously addresses environmental protection and resource recovery imperatives.
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