PL EN
Tetracycline uptake by photoaged polypropylene and high-density polyethylene microplastics in water
 
Więcej
Ukryj
1
Department of Environmental Engineering, Faculty of Civil Engineering and Planning, Universitas Islam Indonesia, Jl. Kaliurang Km. 14.5, Yogyakarta 55584, Indonesia
 
2
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia, Jl. Kaliurang Km. 14.5, Yogyakarta 55584, Indonesia
 
 
Autor do korespondencji
Puji Lestari   

Department of Environmental Engineering, Faculty of Civil Engineering and Planning, Universitas Islam Indonesia, Jl. Kaliurang Km. 14.5, Yogyakarta 55584, Indonesia
 
 
 
SŁOWA KLUCZOWE
DZIEDZINY
STRESZCZENIE
Microplastics coexist with various contaminants in aquatic environments and may serve as critical sorbents for those contaminants, including tetracycline (TC) antibiotics. In this study, the adsorption behavior of TC on pristine and photoaged polypropylene (PP) and high-density polyethylene (HDPE) microplastics was systematically investigated in aqueous systems. Fourier-transform infrared spectroscopy and scanning electron microscopy were used to observe the structural and surface changes induced by photoaging process. Batch adsorption experiments were conducted to study the effects of contact time, solution pH, and initial TC concentration. Photoaging significantly enhanced TC uptake on both type of polymers, with PP exhibiting a higher adsorption capacity than HDPE. Adsorption on both polymers followed pseudo-second-order kinetics, with photoaged materials exhibited lower rate constants but higher equilibrium capacities. The Langmuir model provided the best fit to equilibrium data, indicating the monolayer coverage of TC on polymer surfaces. The estimated maximum adsorption capacity (Qₘₐₓ) of PP increased by more than twofold following photoaging, rising from 4.15 mg g⁻¹ to 9.22 mg g⁻¹, whereas HDPE exhibited consistently low capacities (1.59 –1.60 mg g⁻¹) regardless of aging. These results demonstrate that polymer type and environmental aging critically govern the role of microplastics as antibiotic carriers in aquatic environments.
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