The ultimate goal of this research is to create effective and environmentally friendly biochar briquettes from oil palm frond (OPF) waste. Red clay, a plentiful local resource, has been demonstrated to improve the properties of fuel briquettes. In this study, the tested composite briquettes (biochar:red clay:starch by weight) were prepared in the following ratios: 40:55:5 (T2), 50:45:5 (T3), 60:35:5 (T4), and 70:25:5 (T5), while the control sample (T1) consisted of 95:5 (biochar:starch). All of the different ratios were analyzed using proximate analysis. The results showed moisture content ranging from 7.35% to 8.47%, ash content from 29.75% to 49.82%, volatile matter from 15.63% to 17.47%, and fixed carbon from 25.31% to 46.48%. Among them, T4 exhibited the lowest moisture and ash content and the highest calorific value at 5,650 cal/g, making it the optimal candidate for further investigation. A comprehensive analysis of T4 was conducted using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray diffraction (XRD). The techniques revealed the morphological structure and inorganic components that contribute to the energy efficiency of T4. The study also examined air pollutant emissions. T4 produced lower emissions of pollutants such as carbon monoxide (CO), carbon dioxide (CO₂), total volatile organic compounds (TVOCs), formaldehyde (HCHO), and particulate matter (PM1.0 and PM2.5) compared to the OPF biochar briquette without red clay (T1). Composite biochar briquettes made from OPF and red clay (T4) are safe and suitable for use as a fuel source for household applications like cooking and heating. This research contributes to the development of the green bioeconomy and supports sustainable energy initiatives.